Linkages among runoff, dissolved organic carbon, and the stable oxygen isotope composition of seawater and other water mass indicators in the Arctic Ocean

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Flow-weighted dissolved organic carbon (DOC) concentrations and delta O-18 values were determined from major arctic rivers, specifically the Ob, Yenisey, Lena, Kolyma, Mackenzie, and Yukon during 2003-2004. These data were considered in conjunction with marine data for DOC, delta O-18 values, nutrients, salinity, and fluorometric indicators of DOC obtained during sampling at the shelf-basin boundary of the Chukchi and Beaufort seas. On the basis of these data, freshwater in the sampled marine waters is likely derived from regional sources, such as the Mackenzie, the Bering Strait inflow, and possibly eastern Siberian rivers, including the Kolyma, or the Lena, but not rivers farther west in the Eurasian arctic. Freshwater from melted sea ice is insignificant over annual cycles, although melted sea ice was a locally dominant freshwater component following summer sea-ice retreat in 2002. DOC concentrations were correlated with the runoff fraction, with an apparent meteoric water DOC concentration of 174 +/- 1 mu M. This is lower than the flow-weighted concentrations measured at river mouths of the five largest Arctic rivers (358 to 917 mu M), indicating removal of DOC during transport through estuaries, shelves and in the deep basin. Flow-weighted DOC concentrations in the two largest North American arctic rivers, the Yukon (625 mu M) and the Mackenzie (358 mu M), are lower than in the three largest Eurasian arctic rivers, the Ob (825 mu M), the Yenesey (858 mu M), and the Lena (917 mu M). A fluorometer responding to chromophoric dissolved organic matter (CDOM) was not correlated with DOC concentrations in Pacific-influenced surface waters unlike previous observations in the Atlantic layer. Nutrient distributions, concentrations, and derived ratios suggest the CDOM fluorometer may be responding to the release of chromophoric materials from shelf sediments. Shipboard incubations of undisturbed sediment cores indicate that sediments on the Bering and Chukchi Sea shelves are a net source of DOC to the Arctic Ocean.